Author Archives: Vincenzo Benessere

Heterogeneous Brønsted Catalysis in the Solvent-Free and Multigram-Scale Synthesis of Polyalcohol Acrylates: The Case Study of Trimethylolpropane Triacrylate

Acrylic acid esters resulting from its reaction with polyalcohols have great relevance in many application areas, such as in the formulation of plastics, adhesives and paints. Their preparation is laborious due to the chemical properties of acrylic acid, which tends to spontaneously polymerize resulting in undesirable products. This paper describes the preparation in high yields of an ester by a convenient catalytic procedure that allows solvent exclusion and catalyst recycling.

Glycerol: a green solvent for synthetic chemistry

Glycerol is a biodegradable, nontoxic, nonvolatile, and water-soluble liquid, qualities that make it valuable in various applications. It is currently obtained as a by-product of biodiesel production in quantities of millions of tons per year. Therefore, to make biodiesel production sustainable, its full potential must be exploited. This review describes its fruitful use as a solvent of relevant synthetic importance.

Fluorine-Free Lithium-Ion Capacitor with Enhanced Sustainability and Safety Based on Bio-Based ƴ-Valerolactone and Lithium Bis(Oxalate)Borate Electrolyte

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Solvents are indispensable components of chemical manufacturing. Traditional ones are derived from depleting fossil sources and are often flammable and harmful. These articles describe green solvents derived from waste cellulose, and their application in chemical reactions and modern energy storage devices, such as batteries and supercapacitors.

Totally Recyclable Catalystis for esterification reactions

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This patent was the launching pad for Isuschem to start industrial production: it claims the green invention to convert fractions of waste vegetable oils into ingredients for many applications. The methodology produces no by-products, has simple processing, and allows recycling of the zinc-based catalyst.

Circular bioeconomy: a virtuous combination for a sustainable future

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A great challenge. In a world grappling with the pressing challenges of climate change and resource depletion, the Circular Bioeconomy can be called an innovative and promising model for sustainable development. It is a new economic model that integrates the principles of the circular economy with those of the Bioeconomy, and aims to make efficient […]

Unveiling Stereo-Electronic Effects in Homogeneous Catalysis Integrating Theory and Experiments: the Potential of Dimeric Iron(III) Salen Complexes in Methyl Levulinate Transesterification

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Important raw materials are obtained from waste pulp from the wood and paper industry. These include levulinic acid, from the processing of which we obtain fuel additives, plasticizers and cosmetic ingredients. These articles describe sustainable methods for their preparation by convenient iron(III)-based catalysts.

First Edition of BioInvestIT: Isuschem among the 10 most promising Italian startups in the Circular Bioeconomy.

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Green chemistry that wants to revolutionize industrial processes. Isuschem has been selected among the 10 most promising Italian startups in the Circular Bioeconomy.On May 14 in Milan , we presented our innovative project to local and European investors , aiming to get enough funds to launch our business. We are proud to have joined the […]

Frying oil: waste or valuable resource?

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Even the most common raw materials can hide great potential. How many times after frying something have you emptied the pan full of oil, which is definitely too dark and opaque to be reused?Perhaps, rather casually, you poured it down the sink or a drain and let this organic matter dissipate.Well, you made a mistake.That […]

1,3-Dioxolane compounds (DOXs) as biobased reaction media

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Solvents are indispensable components of chemical manufacturing. Traditional ones are derived from depleting fossil sources and are often flammable and harmful. These articles describe green solvents derived from waste cellulose, and their application in chemical reactions and modern energy storage devices, such as batteries and supercapacitors.

Biodiesel from Waste Cooking Oil: Highly Efficient Homogeneous Iron(III) Molecular Catalysts.

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Frying oils as feedstock for biofuels: these articles describe sustainable methodologies for preparing biodiesel from domestic or catering frying oils. The use of inexpensive and highly available iron-based catalysts returns the biofuel in high quantities without the need for purification or sophisticated manipulation.